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Clausius-Mosotti at the Nanoscale: Spontaneously
Polarized States
Professor Philip B. Allen
Dept. of Physics and Astronomy, SUNY Stony Brook, and
Dept. of Applied Physics and Applied Mathematics, Columbia University
The Clausius-Mosotti theorem shows that an infinite and
translationally invariant collection of point polarizable
molecules has an effective polarizability that is enhanced by
the factor (1- relative to the polarizability
a of uncoupled dipoles. If
is large enough that the denominator
vanishes, a spontaneously polarized state can occur. This is the
simplest microscopic model of ferroelectricity. In this informal
talk I will discuss what happens in some model nanocrystals, and
how the Clausius-Mosotti formula evolves when you progress from
nanocrystals toward the bulk. |