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Growth and Characterization of
Ultrathin Epitaxial Graphite films on Silicon CarbideTianbo Li
Georgia Tech
School of Physics
Ultrathin graphite films grown on the 4H/6H
SiC (0001) surface - a platform for ballistic-carrier devices based on
nano-patterned epitaxial graphene - were investigated through Auger
electron spectroscopy, low energy electron diffraction (LEED) and
scanning tunneling microscopy (STM). Graphite films, several graphene
layers thick, were grown on both the Si- and C-terminated faces via
thermal desorption of silicon. STM imaging was used to identify a
modified reconstruction
layer between graphene layers and the SiC substrate.
Through comparison of STM and LEED results,
a complex LEED
pattern has been found to arise from the modified
reconstruction
layer, a surface corrugation of the graphene film, and from double
scattering. Prior interpretations attributed the LEED pattern to double
scattering effects alone. STM images indicate that the graphite films
are continuous over substrate steps, but differences in the local
electronic structure exist between adjacent domains, as determined via
tunneling current versus voltage spectroscopy. |