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Electron-Impact Ionization Of Atoms: Finally
Solving The Most Basic Example. C. William McCurdy
Lawrence Berkeley National Laboratory
Electron impact ionization of atoms and molecules is one of
the most basic phenomena in low-energy collision physics. It is
responsible for forming and sustaining low-temperature plasmas that are
used in applications ranging from fluorescent lighting to the processing
of silicon chips. Since the invention of quantum mechanics, even the
simplest example of the collisional breakup of a system of charged
particles,
,has
resisted solution, never having been ˇ§reduced to computationˇ¨. The reason is that, even though the asymptotic form of
the wave function for ionization was first given by Peterkop and Rudge
almost 40 years ago, the formal
theory of ionization has thus far proved too difficult to apply in a
complete
scattering
calculation ˇV even with modern massively parallel
supercomputers. We have solved this problem by an approach that
separates the computation of the wave function from the calculation
of cross sections from it.
The story involves exotic
mathematics, basic quantum mechanics, and large-scale computation, and
appeared on the cover of last issue of Science in the
1900s [Rescigno, Baertschy, Isaacs and McCurdy, Science, 286,
2474 (1999)]. This seminar will tell that story and describe
developments in accurate calculations on electron-impact ionization
since then. |